Highly efficient aqueous phase chemoselective hydrogenation of α,β-unsaturated aldehydes catalysed by phosphine-decorated polymer immobilized IL-stabilized PdNPs†‡,10.1039/C6GC03528K

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Highly efficient aqueous phase chemoselective hydrogenation of α,β-unsaturated aldehydes catalysed by phosphine-decorated polymer immobilized IL-stabilized PdNPs†‡

S. Doherty,J. G. Knight,T. Backhouse,E. Abood,H. Alshaikh,I. J. S. Fairlamb,R. A. Bourne,T. W. Chamberlain,R. Stones

Green Chemistry Pub Date : 01/26/2017 00:00:00 , DOI:10.1039/C6GC03528K

Abstract

Phosphino-decorated polymer immobilised ionic liquid phase stabilised palladium nanoparticles (PdNP@PPh₂-PIILP) and their PEGylated counterparts (PdNP@PPh₂-PEGPIILP) are remarkably active and exceptionally selective catalysts for the aqueous phase hydrogenation of α,β-unsaturated aldehydes, ketones, esters and nitriles with PdNP@PPh₂-PEGPIILP giving complete conversion and 100% selectivity for reduction of the C [double bond, length as m-dash] C bond, under mild conditions. This is the most selective PdNP-based system to be reported for the aqueous phase hydrogenation of this class of substrates.