960化工网
Homogeneous freezing nucleation rates and crystallization dynamics of single levitated sulfuric acid solution droplets
Hermann Vortisch,Benedikt Krämer,Inez Weidinger,Ludger Wöste,Thomas Leisner,Martin Schwell,Helmut Baumgärtel,Eckart Rühl
Physical Chemistry Chemical Physics Pub Date : 03/10/2000 00:00:00 , DOI:10.1039/A908225E
Abstract

Supercooled sulfuric acid solution droplets are a major constituent of the stratospheric background aerosol. We report the rate of homogeneous freezing and the crystallization dynamics of single levitated sulfuric acid solution droplets with 0 to 57.6 wt.% H2SO4. The energy of formation of the critical nucleus and the self-diffusion activation energy are deduced from the experiments as a function of temperature and concentration. The results are compared to both theoretical and experimental work of other groups.

平台客服
平台客服
平台在线客服