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Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes†
Slawomir Urban,Roland Fröhlich,Frank Glorius
Dalton Transactions Pub Date : 07/17/2009 00:00:00 , DOI:10.1039/B908981K
Abstract

The investigation of the electronic and steric properties of 4,5-disubstituted imidazolylidenes is reported, as well as their successful application as organocatalysts in the formation of γ-butyrolactones by conjugate Umpolung.

Graphical abstract: Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes
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