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Iron(ii) spin transition coordination polymers with a zigzag structure†
Wolfgang Bauer,Marinela M. Dîrtu,Yann Garcia,Birgit Weber
CrystEngComm Pub Date : 12/22/2011 00:00:00 , DOI:10.1039/C2CE06253D
Abstract

The synthesis and characterisation of seven iron(II) 1D chain coordination polymers with tetradentate Schiff-base like equatorial ligands and bis(4-pyridylmethyl)sulfide (bpms) as a flexible bridging axial ligand is reported. This new family of materials displays a wide spectrum of spin transition properties in the solid state ranging from gradual, abrupt, incomplete to even step-wise that have all been characterized by SQUID magnetometry. The X-ray structure analysis of two complexes at several temperatures is discussed in the frame of their spin crossover properties.

Graphical abstract: Iron(ii) spin transition coordination polymers with a zigzag structure
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