Excessive pesticide residues are a serious problem faced by food regulatory authorities, suppliers, and consumers. To assist with this challenge, this work aimed to develop a method of detecting and classifying pesticide residue on fruit samples using an electronic nose, through the application of three different data-recognition algorithms. The apple samples carried various concentrations of two known pesticides, namely cypermethrin and chlorpyrifos. Data collection was performed using a PEN3 electronic nose equipped with 10 metal oxide semiconductor (MOS) sensors. In order to classify and analyze these pesticide residues on the apple samples, principal component analysis (PCA), linear discriminant analysis (LDA), and support vector machine (SVM) results were combined with sensor output responses to realize MOS sensor array data visualization. The results indicated that all three data-recognition algorithms accurately identified the pesticide residues in the apple samples, with the PCA algorithm exhibiting the best classification and discrimination ability. Consequently, this work has shown that the MOS electronic nose, in combination with data-recognition algorithms, can provide support for the rapid and non-destructive identification of pesticide residues in fruits and can provide an effective tool for the detection of pesticide residues in agricultural products.