Hydrogen peroxide production via a redox reaction of N,N′-dimethyl-2,6-diaza-9,10-anthraquinonediium by addition of bisulfite†,10.1039/C8CC05548C

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Hydrogen peroxide production via a redox reaction of N,N′-dimethyl-2,6-diaza-9,10-anthraquinonediium by addition of bisulfite†

Igor V. Kolesnichenko,P. Rogelio Escamilla,Jason A. Michael,Vincent M. Lynch,David A. Vanden Bout,Eric V. Anslyn

Chemical Communications Pub Date : 09/13/2018 00:00:00 , DOI:10.1039/C8CC05548C

Abstract

We demonstrate that bisulfite can be used for reduction of a highly electrophilic anthraquinone derivative, N,N′-dimethyl-2,6-diaza-9,10-anthraquinonediium (DAAQ), and subsequent autoxidation generates an equivalent of hydrogen peroxide. The mechanism for DAAQ reduction by bisulfite, DAAQ electrochemistry, and use of a simple test strip assay for H₂O₂, are described.