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Lanthanide luminescent anion sensing: evidence of multiple anion recognition through hydrogen bonding and metal ion coordination†
Cidália M. G. dos Santos,Pablo Barrio Fernández,Sally E. Plush,Joseph P. Leonard,Thorfinnur Gunnlaugsson
Chemical Communications Pub Date : 06/15/2007 00:00:00 , DOI:10.1039/B705560A
Abstract

The delayed lanthanide luminescence of the terbium [Tb(III)] diaryl-urea complex 1·Tb is significantly enhanced upon sensing of dihydrogenphosphate (H2PO4−) in CH3CN, which occurs through multiple anion binding through hydrogen bonding interactions and potential metal ion coordination to Tb(III).

Graphical abstract: Lanthanide luminescent anion sensing: evidence of multiple anion recognition through hydrogen bonding and metal ion coordination
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