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A novel 2D infinite M3L2 cage-based Cd(ii) microporous coordination polymer with a tripodal carboxylic acid ligand and solvent-dependent luminescence properties†
Shizhen Yuan,Fazhi Xie,Yi Ding,Meng Zhao,Shichao Wang,Hao Li,Shengyi Zhang,Jieying Wu,Yupeng Tian
New Journal of Chemistry Pub Date : 11/17/2015 00:00:00 , DOI:10.1039/C5NJ02144H
Abstract

A novel M3L2 cage-based microporous coordination polymer assembled from the six-coordinated Cd(II) ion and a flexible tricarboxylic ligand has been designed and synthesized. The solvent-dependent luminescence properties revealed that the coordination polymer has an obvious, enhanced luminescence in the solvents CH2Cl2 and CHCl3.

Graphical abstract: A novel 2D infinite M3L2 cage-based Cd(ii) microporous coordination polymer with a tripodal carboxylic acid ligand and solvent-dependent luminescence properties
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