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Halogen bonding two-point recognition with terphenyl derivatives†
J. Stoesser,G. Rojas,D. Bulfield,P. I. Hidalgo,J. Pasán,C. Ruiz-Pérez,C. A. Jiménez,S. M. Huber
New Journal of Chemistry Pub Date : 04/12/2018 00:00:00 , DOI:10.1039/C8NJ00962G
Abstract

Two-point recognition involving neutral terphenyl-based halogen bond donors (halogen-based Lewis acids) was investigated. Oxadiazole and pyridazole derivatives were identified by DFT as suitable binding partners, even though gas-phase binding was weak. X-ray studies provided convincing evidence of two-point binding in the solid state, while solution data hinted at weak association.

Graphical abstract: Halogen bonding two-point recognition with terphenyl derivatives
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