Ligand control in the photochemical generation of high-valent porphyrin-iron–oxo derivatives†,10.1039/C5CC02852C

批量搜索

批量搜索

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Ligand control in the photochemical generation of high-valent porphyrin-iron–oxo derivatives†

Tse-Hong Chen,Nawras Asiri,Ka Wai Kwong,Jonathan Malone,Rui Zhang

Chemical Communications Pub Date : 05/18/2015 00:00:00 , DOI:10.1039/C5CC02852C

Abstract

Visible-light irradiation of photo-labile bromate porphyrin-iron(III) salts gave iron(IV)–oxo porphyrin radical cations (compound I model) or the neutral iron(IV)–oxo porphyrin (compound II model), depending on the electronic structure of porphyrin ligands.