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Hierarchically porous CoNiO2 nanosheet array films with superior sodium storage performance†
Ling Chang,Kai Wang,Liangai Huang,Zhishun He,Haibo Shao,Jianming Wang
New Journal of Chemistry Pub Date : 10/31/2017 00:00:00 , DOI:10.1039/C7NJ03241B
Abstract

Nanostructured transition metal oxides are considered as some of the promising anode materials for rapidly emerging sodium ion batteries. Herein, a hierarchically porous CoNiO2 nanosheet array film is prepared via a low-temperature solvothermal method with subsequent annealing treatment. As a self-supported anode for sodium ion batteries (SIBs), the as-prepared hierarchically porous CoNiO2 nanosheet array film manifests superior sodium storage performance. The film electrode delivers a large reversible capacity of 746.6 mA h g−1 after 100 cycles at 200 mA g−1. In particular, a capacity of 419 mA h g−1 is achieved at a high current density of 1600 mA g−1, demonstrating a good rate capability.

Graphical abstract: Hierarchically porous CoNiO2 nanosheet array films with superior sodium storage performance
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