Kumada–Tamao–Corriu coupling reaction catalyzed by transition-metal has been widely used in organic synthesis. Organic halides are mostly used as electrophiles in this reaction. Compared with organic halides, O-based electrophiles are less explored. In this review, we summarized the Kumada–Tamao–Corriu coupling reaction of O-based electrophiles, including sulfonates, phosphates, ethers, and carboxylates.