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La0.4Gd1.6Zr2O7:0.1%Pr transparent sintered ceramic – a wide-range luminescence thermometer†
Joanna Trojan-Piegza,Carlos D. S. Brites,João F. C. B. Ramalho,Zhengjuan Wang,Guohong Zhou,Shiwei Wang
Journal of Materials Chemistry C Pub Date : 04/29/2020 00:00:00 , DOI:10.1039/D0TC00861C
Abstract

Sintered transparent ceramics, presenting extraordinary resistance to thermal shocks, incomparably larger than glasses, glass ceramics, and single crystals, maybe valuable luminescence thermometers especially for high-temperature applications. The literature on that subject is, however, very much limited at present. In this paper, the performance of La0.4Gd1.6Zr2O7:0.1%Pr3+ sintered transparent ceramics as a luminescence thermometer was investigated. Temperature dependence of the intensity ratio of emissions from 3P0 and 1D2 levels of the Pr3+ activator was found useful to measure temperature with reasonable relative sensitivity and accuracy over the 15–650 K range – one of the broadest achievable up to date. Time-resolved spectroscopy enabled distinct emissions from 1D2 and 3P0 in the red part of the spectrum. This allowed achieving an impressive relative sensitivity of the La0.4Gd1.6Zr2O7:0.1%Pr luminescence thermometer which exceeded 0.81% K−1 at 650 K.

Graphical abstract: La0.4Gd1.6Zr2O7:0.1%Pr transparent sintered ceramic – a wide-range luminescence thermometer
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