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Low temperature and limited water activity reveal a pathway to magnesite via amorphous magnesium carbonate†
Sebastian T. Mergelsberg,Sebastien N. Kerisit,Eugene S. Ilton,Odeta Qafoku,Christopher J. Thompson,John S. Loring
Chemical Communications Pub Date : 09/08/2020 00:00:00 , DOI:10.1039/D0CC04907G
Abstract

Forsterite carbonated in thin H2O films to magnesite via amorphous magnesium carbonate during reaction with H2O-bearing liquid CO2 at 25 °C. This novel reaction pathway contrasts with previous studies that were carried out at higher H2O activity and temperature, where more highly hydrated nesquehonite was the metastable intermediate.

Graphical abstract: Low temperature and limited water activity reveal a pathway to magnesite via amorphous magnesium carbonate
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