Highly diastereoselective formation of C2-symmetric bis-thioglycoside Pd(ii) complexes: the role of the exo anomeric effect†
Noureddine Khiar,Cristina S. Araújo,Bélen Suárez,Eleuterio Alvarez,Inmaculada Fernández
Chemical Communications Pub Date : 02/16/2004 00:00:00 , DOI:10.1039/B313798H
Abstract
Treatment of several C2 symmetric bis-thioglycosides with Pd(CH3CN)2Cl2 always leads to a single diastereomeric Pd(II) complex as a consequence of the exo-anomeric effect.
