Highly emissive, nine-coordinate enantiopure lanthanide complexes incorporating tetraazatriphenylenes as probes for DNA†
Gabriella Bobba,Juan C. Frias,David Parker
Chemical Communications Pub Date : 03/25/2002 00:00:00 , DOI:10.1039/B201451N
Abstract
The interaction of q = 0 Δ- and Λ-Tb and Eu complexes with poly(dAdT), poly(dGdC) and calf-thymus DNA has been examined by absorption, emission and chiroptical spectroscopy and is sensitive to complex helicity, base-pair type and the nature of the lanthanide excited state.