Insoluble surfactant spreading along thin liquid films confined by chemical surface patterns
David K. N. Sinz,Myroslava Hanyak,Jos C. H. Zeegers,Anton A. Darhuber
Physical Chemistry Chemical Physics Pub Date : 04/18/2011 00:00:00 , DOI:10.1039/C0CP02135K
Abstract

We conducted a combined experimental and numerical study of the spreading of insoluble surfactants on spatially confined thin liquid films. We found that the spreading dynamics can locally be represented by a power-law relation xtα. We determine the time evolution of the liquid film thickness and the corresponding spreading exponents α both from experiments using interference microscopy and numerical finite element simulations. The lateral confinement induces non-uniform height- and surface velocity profiles, which manifest themselves in a pronounced transition of the evolving rivulet morphology. Excellent agreement between experimental and simulation results has been achieved.

Graphical abstract: Insoluble surfactant spreading along thin liquid films confined by chemical surface patterns