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M©B7O7+ (M = Ni, Pd, Pt): aromatic molecular stars with a planar heptacoordinate transition metal†
Bo Jin,Rui Sun,Bin Huo,Caixia Yuan,Yan-Bo Wu
Chemical Communications Pub Date : 11/29/2021 00:00:00 , DOI:10.1039/D1CC05844D
Abstract

The dynamically stable global minima M©B7O7+ (M = Ni, Pd, Pt) are interesting in that they possess σ-aromaticity alone within the B7M core moiety, which can be attributed to the strong peripheral localized O → B π back-bonding that leads to the less favourable delocalized M → B π back-bonding over the B7M core moiety.

Graphical abstract: M©B7O7+ (M = Ni, Pd, Pt): aromatic molecular stars with a planar heptacoordinate transition metal
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