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A novel scandium fluoride, [C2N2H10]0.5[ScF4], with an unprecedented tungsten bronze-related layer structure.
Nicholas F. Stephens,Alexandra M. Z. Slawin,Philip Lightfoot
Chemical Communications Pub Date : 02/09/2004 00:00:00 , DOI:10.1039/B316312A
Abstract

[C2N2H10]0.5[ScF4] exhibits isolated anionic layers of corner-linked ScF6 octahedra enclosing 3-, 4-, 5- and 6-membered rings, with features reminiscent of both hexagonal and tetragonal tungsten bronze-type structures.

Graphical abstract: A novel scandium fluoride, [C2N2H10]0.5[ScF4], with an unprecedented tungsten bronze-related layer structure.
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