Chemical Communications Pub Date : 02/11/2004 00:00:00 , DOI:10.1039/B312954C
Abstract
The novel dimer [Cp2Zr⊖S⊕CH(Ph)CHCPPh2]2, the first example of a structurally characterised sulfur-bridged binuclear zirconathiolane complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some aspects of its solution behaviour were studied.
![[upper bond 1 start]](http://www.rsc.org/images/entities/char_e010.gif)
⊖S⊕CH(Ph)CH![[double bond, length as m-dash]](http://www.rsc.org/images/entities/char_e001.gif)
C![[upper bond 1 end]](http://www.rsc.org/images/entities/char_e011.gif)
PPh2]2, the first example of a structurally characterised sulfur-bridged binuclear zirconathiolane complex, was prepared, characterised by 
