I2-catalyzed oxidative C(sp3)–H/S–H coupling: utilizing alkanes and mercaptans as the nucleophiles†,10.1039/C4CC05661B

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

I2-catalyzed oxidative C(sp3)–H/S–H coupling: utilizing alkanes and mercaptans as the nucleophiles†

Jiwen Yuan,Xu Ma,Hong Yi,Chao Liu

Chemical Communications Pub Date : 09/26/2014 00:00:00 , DOI:10.1039/C4CC05661B

Abstract

By using alkanes and mercaptans as the nucleophiles with di-tert-butyl peroxide (DTBP) as the oxidant, I₂-catalyzed oxidative C(sp³)–H/S–H coupling was achieved. This protocol provides a novel process to construct C(sp³)–S bonds from commercially available hydrocarbons and mercaptans.