960化工网
MOF positioning technology and device fabrication†
Paolo Falcaro,Raffaele Ricco,Cara M. Doherty,Kang Liang,Anita J. Hill,Mark J. Styles
Chemical Society Reviews Pub Date : 05/07/2014 00:00:00 , DOI:10.1039/C4CS00089G
Abstract

Metal organic frameworks (MOFs) offer the highest surface areas per gram of any known material. As such, they epitomise resource productivity in uses where specific surface area is critical, such as adsorption, storage, filtration and catalysis. However, the ability to control the position of MOFs is also crucial for their use in devices for applications such as sensing, delivery, sequestration, molecular transport, electronics, energy production, optics, bioreactors and catalysis. In this review we present the current technologies that enable the precise positioning of MOFs onto different platforms. Methods for permanent localisation, dynamic localisation, and spatial control of functional materials within MOF crystals are described. Finally, examples of devices in which the control of MOF position and functionalisation will play a major technological role are presented.

Graphical abstract: MOF positioning technology and device fabrication
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