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Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm†
Thomas Weyrich,Jan Krahmer,Tobias A. Engesser,Christian Näther,Felix Tuczek
Dalton Transactions Pub Date : 01/31/2019 00:00:00 , DOI:10.1039/C8DT04738C
Abstract

We report the first molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand. By employing several spectroscopic methods we are able to pinpoint the pentaphosphine environment and evaluate the activation of the dinitrogen ligand. Furthermore, we conduct protonation experiments and obtain spectroscopic evidence for the formation of a hydrazido-species.

Graphical abstract: Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm
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