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Incorporation of uranium(vi) into metal–organic framework solids, [UO2(C4H4O4)]·H2O, [UO2F(C5H6O4)]·2H2O, and [(UO2)1.5(C8H4O4)2]2[(CH3)2NCOH2]·H2O
Jong-Young Kim,Alexander J. Norquist,Dermot O'Hare
Dalton Transactions Pub Date : 06/23/2003 00:00:00 , DOI:10.1039/B306733P
Abstract

Uranium–organic framework solids, in which uranium building units are connected by bidentate dicarboxylate anions such as succinate, glutarate, and isophthalate, were synthesized; the glutarate and isophthalate compounds contain cavities, in which occluded water and organic templates reside.

Graphical abstract: Incorporation of uranium(vi) into metal–organic framework solids, [UO2(C4H4O4)]·H2O, [UO2F(C5H6O4)]·2H2O, and [(UO2)1.5(C8H4O4)2]2[(CH3)2NCOH2]·H2O
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