A novel strategy for the asymmetric synthesis of chiral cyclopropane carboxaldehydes†,10.1039/B501847A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

A novel strategy for the asymmetric synthesis of chiral cyclopropane carboxaldehydes†

Matt Cheeseman,Fred J. P. Feuillet,Andrew L. Johnson,Steven D. Bull

Chemical Communications Pub Date : 03/17/2005 00:00:00 , DOI:10.1039/B501847A

Abstract

A new way of combining chiral auxiliaries and substrate-directable reactions for asymmetric synthesis is described that employs a three-step sequence of aldol–cyclopropanation–retro-aldol reactions for the stereoselective synthesis of enantiopure cyclopropane carboxaldehydes.