A perylene complex with a one-dimensional coordination polymer containing [Mn6O2(CHCl2COO)10(H2O)2] cluster units linked by 3,10-perylenequinone bridges†,10.1039/C6NJ03097A

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

A perylene complex with a one-dimensional coordination polymer containing [Mn6O2(CHCl2COO)10(H2O)2] cluster units linked by 3,10-perylenequinone bridges†

Lyudmila A. Kushch,Anna V. Kazakova,Svetlana A. Mironova,Eduard B. Yagubskii,Sergey V. Simonov,Leokadiya V. Zorina,Rimma P. Shibaeva,Andrey V. Sadakov,Vladimir S. Mironov

New Journal of Chemistry Pub Date : 12/13/2016 00:00:00 , DOI:10.1039/C6NJ03097A

Abstract

The crystals of a perylene complex with the polymeric cluster containing [Mn₆O₂(O₂CCHCl₂)₁₀(H₂O)₂] units assembled by 3,10-perylenequinone bridges, {[Mn₆O₂(O₂CCHCl₂)₁₀(H₂O)₂(C₂₀H₁₀O₂)]_2n路(C₂₀H₁₂)_n} (I), were obtained in the reaction of [Mn₁₂O₁₂(O₂CCHCl₂)₁₆(H₂O)₄] with perylene. Unlike the Mn12 oxodichloroacetate cluster, the reaction of the Mn12 oxobenzoate cluster, [Mn₁₂O₁₂(O₂CPh)₁₆(H₂O)₄], with perylene does not occur. However, it turned out that the crystals isolated from the reaction are a new Mn12 oxobenzoate cluster containing three molecules of coordinated H₂O and solvate molecules of hexane, [Mn₁₂O₁₂(O₂CC₆H₅)₁₆(H₂O)₃]路2C₆H₁₂ (II). Crystal structures of complexes I and II as well as the magnetic properties of the former were studied.