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Methyl formate as a carbonylating agent for the catalytic conversion of phenol to methyl phenyl carbonate†
Mohammad S. Yalfani,Giulio Lolli,Aurel Wolf,Leslaw Mleczko,Thomas E. Müller
Green Chemistry Pub Date : 03/12/2013 00:00:00 , DOI:10.1039/C3GC36877G
Abstract

Methyl formate was used as a green and efficient carbonylating agent in the synthesis of methyl phenyl carbonate from phenol. Methyl formate showed better performance compared to toxic CO gas and the ability to produce other useful carbonylated products, e.g., dimethyl carbonate and dimethyl oxalate.

Graphical abstract: Methyl formate as a carbonylating agent for the catalytic conversion of phenol to methyl phenyl carbonate
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