Merging metal–organic framework catalysis with organocatalysis: A thiourea functionalized heterogeneous catalyst at the nanoscale†,10.1039/C3CY00864A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Merging metal–organic framework catalysis with organocatalysis: A thiourea functionalized heterogeneous catalyst at the nanoscale†

Yi Luan,Nannan Zheng,Yue Qi,Jia Tang,Ge Wang

Catalysis Science & Technology Pub Date : 01/06/2014 00:00:00 , DOI:10.1039/C3CY00864A

Abstract

A new thiourea-containing metal–organic framework (MOF) catalyst was synthesized. It overcomes recycling, self-aggregation and solvation issues that exist in homogeneous thiourea catalysts. Nanomorphology was introduced to increase the dispersion of the solid catalyst in solvent. Acetalization and Morita–Baylis–Hillman reactions were catalyzed using the new thiourea MOF catalyst.