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Isolation and phototransformation of enantiomerically pure iridium(iii) bis[(4,6-difluorophenyl)pyridinato-N,C2]picolinate†
Yue Wang,Takunori Harada,Yoshihito Shiota,Kazunari Yoshizawa,Heng Wang,Sheng Wang,Xichong Ye,Masamichi Ogasawara
RSC Advances Pub Date : 06/06/2017 00:00:00 , DOI:10.1039/C7RA04141A
Abstract

Here we report the resolution of phosphorescent light-emitting iridium(III) bis[(4,6-difluorophenyl)pyridinato-N,C2]-picolinate into its respective enantiomers by using chiral HPLC and the photo-induced transformation of the isolated enantiomers.

Graphical abstract: Isolation and phototransformation of enantiomerically pure iridium(iii) bis[(4,6-difluorophenyl)pyridinato-N,C2]picolinate
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