A novel nonanuclear CuII carboxylate-bridged cluster aggregate with an S = 7/2 ground spin state,10.1039/B316233H

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

A novel nonanuclear CuII carboxylate-bridged cluster aggregate with an S = 7/2 ground spin state

Muralee Murugesu,Philippa King,Rodolphe Clérac,Christopher E. Anson,Annie K. Powell

Chemical Communications Pub Date : 02/23/2004 00:00:00 , DOI:10.1039/B316233H

Abstract

The Cu^II aggregate in [Cu₉(cpida)₆(MeOH)₆]·6(MeOH) {H₃cpida = 2-(carboxyphenyl)iminodiacetic acid} is made up of two weakly ferromagnetically coupled carboxylate-bridged Cu₄ units that are antiferromagnetically linked through a central Cu^II to give a Cu₉ core with an S = 7/2 spin ground state.