On the tuning of electric conductance of extended metal atom chains via axial ligands for [Ru3(μ3-dpa)4(X)2]0/+ (X = NCS−, CN−)†
Kai-Neng Shih,Min-Jie Huang,Hao-Cheng Lu,Ming-Dung Fu,Ching-Kuo Kuo,Gin-Chen Huang,Gene-Hsiang Lee,Chun-hsien Chen,Shie-Ming Peng
Abstract
The influence of a π-acid cyanide axial ligand on the metal–metal interactions of [Ru3(μ3-dpa)4(X)2]0/+ (X = NCS−, CN−) is manifested by the measurements of single-molecule conductance coupled with in situ electrochemical control.
![Graphical abstract: On the tuning of electric conductance of extended metal atom chains via axial ligands for [Ru3(μ3-dpa)4(X)2]0/+ (X = NCS−, CN−)](http://hg.y866.cn/compound/lib/scimg/usr/1/B916677G.jpg)
