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NH3-SCR activity, hydrothermal stability and poison resistance of a zirconium phosphate/Ce0.5Zr0.5O2 catalyst in simulated diesel exhaust
Jun Yu,Zhichun Si,Man Zhu,Lei Chen,Jinshuo Zou
RSC Advances Pub Date : 09/28/2015 00:00:00 , DOI:10.1039/C5RA10653B
Abstract

A ZP/CZ (zirconium phosphate/Ce0.5Zr0.5O2) catalyst exhibits over 80% NOx conversion from 250 to 450 °C under a high GHSV of 300 000 h−1 in the presence of H2O, CO2 and C3H8. Mixing with soot leads to a decrease in NOx conversion of the catalyst at temperatures higher than 350 °C. After hydrothermal aging (760 °C for 48 h) and sulfur aging (400 °C for 48 h), ZP/CZ still possesses over 80% NOx conversions in 289–450 °C and 297–466 °C respectively, which are significantly better than those of home made Cu-SAPO-34 and vanadium catalysts at higher temperatures. These results indicate that ZP/CZ is a promising catalyst for NOx abatement for diesel engine exhausts.

Graphical abstract: NH3-SCR activity, hydrothermal stability and poison resistance of a zirconium phosphate/Ce0.5Zr0.5O2 catalyst in simulated diesel exhaust
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