An efficient, catalytic, diastereo- and enantioselective conjugate addition of N-(diphenylmethylene)glycine tert-butyl ester to β-aryl substituted enones was realized in the presence of 1 mol% of newly desired dinuclear N-spiro-ammonium salts, affording functionalized α-amino acid derivatives in 57–98% yields with high diastereoselectivity (up to 99 : 1 dr) and enantioselectivity (up to 96.5 : 3.5 er).