960化工网
Low photoactive phase temperature all-inorganic, tin–lead mixed perovskite solar cell†
Chun-Hsiao Kuan,Hui-Hung Shen
RSC Advances Pub Date : 01/15/2021 00:00:00 , DOI:10.1039/D0RA10110A
Abstract

CsPbI3 films have recently attracted significant attention as efficient absorbers for thermally stable photovoltaic devices. However, their large bandgap and photoactive black phase formation at high temperature impede their use for practical applications. Using the concept of lattice contraction, we demonstrate a low bandgap (≤1.44 eV) cesium-based inorganic perovskite CsPbxSn1−xI3 that can be solution processed at low temperature for photovoltaic devices. The results from systematic measurements imply that the partial substitution of lead (Pb) with tin (Sn) results in crystal lattice contraction, which is essential for realizing photoactive phase formation at l00 °C and stabilizing photoactive phase at room temperature. These findings demonstrate the potential of using cesium-based inorganic perovskite as viable alternatives to MA- or FA-based perovskite photovoltaic materials.

Graphical abstract: Low photoactive phase temperature all-inorganic, tin–lead mixed perovskite solar cell
平台客服
平台客服
平台在线客服