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Isospecific polymerization of racemic epoxides: a catalyst system for the synthesis of highly isotactic polyethers†
Peter C. B. Widger,Syud M. Ahmed,Wataru Hirahata,Renee M. Thomas,Emil B. Lobkovsky,Geoffrey W. Coates
Chemical Communications Pub Date : 03/22/2010 00:00:00 , DOI:10.1039/B926888J
Abstract

A highly active bimetallic cobalt catalyst system is reported for the polymerization of racemic terminal epoxides to yield isotactic polyethers.

Graphical abstract: Isospecific polymerization of racemic epoxides: a catalyst system for the synthesis of highly isotactic polyethers
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