We demonstrated that two Lewis bases – urea and thiourea – acted as efficient additives for CH3NH3(MA)PbI3−xClx and MAPbI3 perovskite solar cells (PSCs) and observed a significant increase in PCE for the MAPbI3 devices in the presence of 1% urea with a remarkable PCE of 18.8% using an extremely low annealing temperature (85 °C).