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Palladium catalysed cross-dehydrogenative-coupling of 1,3,5-trialkoxybenzenes with simple arenes†
Thomas E. Storr,Faridah Namata,Michael F. Greaney
Chemical Communications Pub Date : 09/08/2014 00:00:00 , DOI:10.1039/C4CC06271J
Abstract

Pd-catalysed cross-dehydrogenative coupling of 1,3,5-trialkoxybenzenes with simple aromatic hydrocarbons is reported. The method enables the coupling of two aromatic C–H positions to generate multi-ortho-substituted biaryls.

Graphical abstract: Palladium catalysed cross-dehydrogenative-coupling of 1,3,5-trialkoxybenzenes with simple arenes
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