Lanthanide separation using size-selective crystallization of Ln-MOFs†,10.1039/C7CC01898C

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Lanthanide separation using size-selective crystallization of Ln-MOFs†

Heng Ya Gao,Wen Li Peng,Pan Pan Meng,Xue Feng Feng,Jian Qiang Li,Hui Qiong Wu,Chang Sheng Yan,Yang Yang Xiong,Feng Luo

Chemical Communications Pub Date : 04/27/2017 00:00:00 , DOI:10.1039/C7CC01898C

Abstract

Herein, we report an elaborate method, size-selective crystallization of Ln-MOFs, to isolate lanthanide (Ln) ions. Herein, 13 lanthanide ions, except for the radioactive Pm(III) ion, were separated by four types of Ln-MOFs: type I (La–Pr), type II (Nd–Eu), type III (Gd–Ho), and type IV (Er–Lu). Further systemic investigation also suggested the highly selective separation of lanthanide ions by this method.