Metal complexes associated with photochromic molecules are attractive platforms to achieve smart light-switching materials with innovative and exciting properties due to specific optical, electronic, magnetic or catalytic features of metal complexes and by perturbing the excited-state properties of both components to generate new reactivity and photochemical properties. In this overview, we focus on selected achievements in key domains dealing with optical, redox, magnetic properties, as well as application in catalysis or supramolecular chemistry. We also try to point out scientific challenges that are still faced for future developments and applications.