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Noncatalytic Heck coupling reaction using supercritical water
Rong Zhang,Masahiro Sato
Chemical Communications Pub Date : 06/02/2003 00:00:00 , DOI:10.1039/B302683C
Abstract

Heck coupling of iodobenzene with styrene can be promoted in supercritical water without using catalyst, and the conversion reaches over 70% within 10 min in the presence of base, such as KOAc, in which case the yield of stilbene is 55.6% (both trans- and cis-stilbene).

Graphical abstract: Noncatalytic Heck coupling reaction using supercritical water
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