Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals†
S. Alan Cramer,Forrest L. Sturgill,Preeti P. Chandrachud,David M. Jenkins
Dalton Transactions Pub Date : 04/15/2014 00:00:00 , DOI:10.1039/C4DT00990H
Abstract

The first tetracarbene complexes of group 13 and 14 metals have been synthesized by employing dianionic macrocyclic tetracarbene ligands. The tin, indium, and aluminium tetracarbene complexes are structurally analogous to their porphyrin or salen analogues. The aluminium complex is the first example of multiple NHCs bound to this metal centre.

Graphical abstract: Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals