Nucleophilic displacement of ammonia from ammonia borane for the preparation of alkylamine-, pyridine- and phosphine-boranes†,10.1039/C4RA03397C

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Nucleophilic displacement of ammonia from ammonia borane for the preparation of alkylamine-, pyridine- and phosphine-boranes†

P. Veeraraghavan Ramachandran,Ameya S. Kulkarni

RSC Advances Pub Date : 05/29/2014 00:00:00 , DOI:10.1039/C4RA03397C

Abstract

A near quantitative and safe preparation of a series of aliphatic amine- and phosphine-boranes from ammonia borane (AB) in refluxing THF has been achieved by exploiting the volatility of ammonia. A one-pot preparation of lithium aminoborohydrides from AB has also been described.