A polymeric bis(di-p-anisylamino)fluorene hole-transport material for stable n-i-p perovskite solar cells†‡
Marie-Hélène Tremblay,Kelly Schutt,Yadong Zhang,Stephen Barlow,Henry J. Snaith,Seth R. Marder
New Journal of Chemistry Pub Date : 02/15/2021 00:00:00 , DOI:10.1039/D0NJ04157B
Abstract

A norbornene homopolymer with hole-transporting 2,7-bis(di-p-anisylamino)fluorene side chains is compared to the widely used spiro-OMeTAD as a hole-transport material (HTM) in negative-intrinsic-positive (n-i-p) perovskite solar cells (PSCs). PSCs fabricated using p-doped homopolymer achieve a power conversion efficiency of 15.5%, comparable to that of cells incorporating p-doped spiro-OMeTAD as the HTM. However, half-devices made with the polymer exhibit improved light and heat stability in comparison to those incorporating spiro-OMeTAD.

Graphical abstract: A polymeric bis(di-p-anisylamino)fluorene hole-transport material for stable n-i-p perovskite solar cells