One-pot synthesis of cyclophane-type macrocycles using manganese(iii)-mediated oxidative radical cyclization†,10.1039/C0OB00683A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

One-pot synthesis of cyclophane-type macrocycles using manganese(iii)-mediated oxidative radical cyclization†

Yosuke Ito,Yuichi Tomiyasu,Takahiro Kawanabe,Keisuke Uemura,Yuu Ushimizu,Hiroshi Nishino

Organic & Biomolecular Chemistry Pub Date : 01/05/2011 00:00:00 , DOI:10.1039/C0OB00683A

Abstract

Cyclophane-type macrocyclic compounds from 21 to 56 members having two fused dihydrofuran rings were synthesized by the manganese(III)-mediated oxidation of terminal dienes with bis(3-oxobutanoate)s containing aromatics. The reaction detail, characterization and reaction pathways are described.