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Optical detection of heterogeneous single molecule diffusion in thin liquid crystal films†
B. Schulz,D. Täuber,F. Friedriszik,H. Graaf,J. Schuster,C. von Borczyskowski
Physical Chemistry Chemical Physics Pub Date : 08/02/2010 00:00:00 , DOI:10.1039/C004042H
Abstract

Lateral diffusion of three different dye molecules (terrylene and two perylene diimides) in 4 to 225 nm thin films of 8CB liquid crystals in the smectic-A phase has been investigated on a single molecule level. The influence of film thickness on tracer diffusion can be qualitatively modeled by a hydrodynamic approach. Molecular tracking experiments as well as fluorescence correlation (FCS) studies reveal the presence of diffusion dynamics which span a range of at least more than one order of magnitude in time, which is much larger than the reported anisotropic self-diffusion observed for 8CB bulk samples. We tentatively assign the heterogeneity to the formation of diffusion limiting domains on a micrometer scale within the 8CB films or at the interfaces.

Graphical abstract: Optical detection of heterogeneous single molecule diffusion in thin liquid crystal films
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