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Metal-free radical perfluoroalkylation of (hetero)arenes†
Sabilla Zhong,Andreas Hafner,Christoph Hussal,Martin Nieger
RSC Advances Pub Date : 12/15/2014 00:00:00 , DOI:10.1039/C4RA13430C
Abstract

We report a metal-free radical perfluoroalkylation method which uses inexpensive and commercially available perfluorocarboxylic anhydrides as an easy to use source of perfluoroalkyl radicals. This approach allows the perfluoroalkylation of different arenes, such as benzene derivatives, furans, thiophenes, and pyrroles, including highly functionalized compounds.

Graphical abstract: Metal-free radical perfluoroalkylation of (hetero)arenes
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