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Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction†
Fupin Liu,Lukas Spree
Chemical Communications Pub Date : 10/07/2019 00:00:00 , DOI:10.1039/C9CC06363C
Abstract

Variable temperature X-ray diffraction studies on two single crystals containing M3N@C80, i.e., Ho2LuN@C80·NiOEP·2(C6H6) and Lu3N@C80·NiOEP·2(C6H6), (NiOEP = Nickel octaethylporphyrin) unravelled the temperature dependent rotation of the M3N cluster and C80 cage on the static NiOEP molecule.

Graphical abstract: Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction
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