Microemulsion-promoted changes of reaction mechanisms:
L. García-Río,J. R. Leis
Chemical Communications Pub Date : 03/01/2000 00:00:00 , DOI:10.1039/A909531D
Abstract
When the hydrolysis of substituted benzoyl chlorides is carried out in a water/oil (w/o) microemulsion, the point in the substituent ς+/lg k plot at which the mechanism changes from associative to dissociative depends on the water content of the microemulsion.