Platinum(ii)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines†
Kristina L. Toups,Ross A. Widenhoefer
Chemical Communications Pub Date : 01/16/2010 00:00:00 , DOI:10.1039/B925859K
Abstract
A 1 ∶ 1 mixture of (dppf)PtCl2 and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 °C to form allylic amines in good yield with selective formation of the E-diastereomer.
