Multicatalysis from renewable resources: a direct route to furan-based polyesters†
Lucie Guillaume,Adam Marshall,Nicolas Niessen,Pingping Ni,Régis M. Gauvin,Christophe M. Thomas
Green Chemistry Pub Date : 08/20/2021 00:00:00 , DOI:10.1039/D1GC01889B
Abstract

Here we present a multicatalytic route to produce 2,5-bis(hydroxymethyl)furan and the corresponding (co)polymers from stable 2,5-furanedicarboxylic acid. This approach combines the use of several commercial catalysts and in particular allows to quantitatively obtain two key furan intermediates, not contaminated by humins.

Graphical abstract: Multicatalysis from renewable resources: a direct route to furan-based polyesters